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Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1] An atom's electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the ...
In general, nucleophilicity decreases as electronegativity increases, meaning that nucleophilicity decreases from left to right across the periodic table. On the other hand, electrophilicity generally increases as electronegativity increases, meaning that electrophilicity follows an increasing trend from left to right on the periodic table. [28]
Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
Periodic table of the chemical elements showing the most or more commonly named sets of elements (in periodic tables), and a traditional dividing line between metals and nonmetals. The f-block actually fits between groups 2 and 3 ; it is usually shown at the foot of the table to save horizontal space.
Periodic variation of Pauling electronegativities as one descends the main groups of the periodic table from the second to the sixth period. Electronegativity is a chemical property that describes the tendency of an atom or a functional group to attract electrons (or electron density) towards itself. [101]
Counterintuitively, E ea does not decrease when progressing down most columns of the periodic table. For example, E ea actually increases consistently on descending the column for the group 2 data. Thus, electron affinity follows the same "left-right" trend as electronegativity, but not the "up-down" trend. The following data are quoted in kJ/mol.
See also: Electronegativities of the elements (data page) There are no reliable sources for Pm, Eu and Yb other than the range of 1.1–1.2; see Pauling, Linus (1960).
Electronegativity values of the group 16 chalcogen elements showing a W-shaped alternation or secondary periodicity going down the group. An alternation in certain periodic trends, sometimes referred to as secondary periodicity, becomes evident when descending groups 13 to 15, and to a lesser extent, groups 16 and 17.