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Molybdenum hexacarbonyl is a popular reagent in academic research. [6]One or more CO ligands can be displaced by other ligands. [7] Mo(CO) 6, [Mo(CO) 3 (MeCN) 3], and related derivatives are employed as catalysts in organic synthesis for example, alkyne metathesis and the Pauson–Khand reaction.
2-Naphthol, or β-naphthol, is a fluorescent colorless (or occasionally yellow) crystalline solid with the formula C 10 H 7 OH. It is an isomer of 1-naphthol , differing by the location of the hydroxyl group on the naphthalene ring.
Halogenation of Mo(CO) 6 gives Mo(II) carbonyl halides, which are also versatile precursors. [7] One large collection of compounds have the formula (C 5 R 5 )Mo(CO) 3 X, derived from cyclopentadienylmolybdenum tricarbonyl dimer (X = halide, hydride, alkyl).
(Mesitylene)molybdenum tricarbonyl arises from the reaction of molybdenum hexacarbonyl with hot mesitylene: [1]. Mo(CO) 6 + (CH 3) 3 C 6 H 3 → Mo(CO) 3 [(CH 3) 3 C 6 H 3] + 3 CO It can also be synthesized, with good yields by displacement of pyridine ligands of the trispyridine complex Mo(CO) 3 (pyridine) 3 in the presence of Lewis acids.
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The six CO ligands are terminal and the Mo-Mo bond distance is 3.2325 Å. [2] The compound is prepared by treatment of molybdenum hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting NaMo(CO) 3 (C 5 H 5). [3] Other methods have been developed starting with Mo(CO) 3 (CH 3 CN) 3 instead of Mo(CO) 6. [4]
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Among the keywords you can find in Connecticut law include "silly string," "balloons" and "arcade games." All these topics are involved in some of the state's strangest laws.