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Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number. The value of 1 unified atomic mass unit in kilograms is m u = 1.660539066 × 10 − 27 k g {\displaystyle m_{\rm {u}}=1.660539066\times 10^{-27}\ \mathrm {kg} } . [ 2 ]
The mass number is different for each isotope of a given chemical element, and the difference between the mass number and the atomic number Z gives the number of neutrons (N) in the nucleus: N = A − Z. [2] The mass number is written either after the element name or as a superscript to the left of an element's symbol.
Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in daltons (making a quantity called the "relative isotopic mass"), is within 1% of the ...
In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [12] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [13]
The standard atomic weight is a special value of the relative atomic mass. It is defined as the "recommended values" of relative atomic masses of sources in the local environment of the Earth's crust and atmosphere as determined by the IUPAC Commission on Atomic Weights and Isotopic Abundances (CIAAW). [2]
The number of nucleons (both protons and neutrons) in the nucleus is the atom's mass number, and each isotope of a given element has a different mass number. For example, carbon-12 , carbon-13 , and carbon-14 are three isotopes of the element carbon with mass numbers 12, 13, and 14, respectively.
A given atom has an atomic mass approximately equal (within 1%) to its mass number times the atomic mass unit (for example the mass of a nitrogen-14 is roughly 14 Da), but this number will not be exactly an integer except (by definition) in the case of carbon-12. [67] The heaviest stable atom is lead-208, [59] with a mass of 207.976 6521 Da. [68]
In general, the mass number of a given nuclide differs in value slightly from its relative atomic mass, since the mass of each proton and neutron is not exactly 1 Da; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and because of the nuclear binding energy and electron binding energy ...