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The structures of solid magnesium citrates have been characterized by X-ray crystallography.In the 1:1 salt, only one carboxylate of citrate is deprotonated. It has the formula Mg(H 2 C 6 H 5 O 7) 2 The other form of magnesium citrate has the formula Mg(HC 6 H 5 O 7)(H 2 O) 2, consisting of the citrate dianion (both carboxylic acids are deprotonated). [1]
As a food additive, potassium citrate is used to regulate acidity, and is known as E number E332. Medicinally, it may be used to control kidney stones derived from uric acid or cystine. In 2020, it was the 297th most commonly prescribed medication in the United States, with more than 1 million prescriptions. [2] [3]
It is a colorless, odorless liquid used as a food additive, emulsifier and solvent (E number E1505) [4] to stabilize foams, especially as whipping aid for egg white. [5] It is also used in pharmaceutical coatings and plastics. [6] Triethyl citrate is also used as a plasticizer for polyvinyl chloride (PVC) and similar plastics. [7]
Sodium citrate is used to prevent donated blood from clotting in storage, and can also be used as an additive for apheresis to prevent clots forming in the tubes of the machine.
Calcium citrate is an intermediate in the isolation of citric acid from the fungal fermentation process by which citric acid is produced industrially. [2] The citric acid in the broth solution is neutralized by limewater, precipitating insoluble calcium citrate.
Its E number is E331. Sodium citrate is employed as a flavoring agent in certain varieties of club soda. It is common as an ingredient in bratwurst, and is also used in commercial ready-to-drink beverages and drink mixes, contributing a tart flavor.
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