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It is a rare blood condition in which the β-pyrrole ring of the hemoglobin molecule has the ability to bind irreversibly to any substance containing a sulfur atom. [1] [2] When hydrogen sulfide (H 2 S) (or sulfide ions) and ferrous ions combine in the heme of hemoglobin, the blood is thus incapable of transporting oxygen to the tissues.
It is slightly soluble in water and acts as a weak acid (pK a = 6.9 in 0.01–0.1 mol/litre solutions at 18 °C), giving the hydrosulfide ion HS −. Hydrogen sulfide and its solutions are colorless. When exposed to air, it slowly oxidizes to form elemental sulfur, which is not soluble in water. The sulfide anion S 2− is not formed in aqueous ...
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
Mustard gas or sulfur mustard are names commonly used for the organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH 2 CH 2 Cl) 2, as well as other species. In the wider sense, compounds with the substituents −SCH 2 CH 2 X or −N(CH 2 CH 2 X) 2 are known as sulfur mustards or nitrogen mustards ...
Sodium sulfide is a chemical compound with the formula Na 2 S, or more commonly its hydrate Na 2 S·9H 2 O.Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid.
Metal toxicity or metal poisoning is the toxic effect of certain metals in certain forms and doses on life. Some metals are toxic when they form poisonous soluble compounds. Certain metals have no biological role, i.e. are not essential minerals, or are toxic when in a certain form. [ 1 ]
Colloidal sulfur (sulfur colloidale) is an extremely fine sulfur powder prepared by repeated precipitation, first from polysulfides with protein and then from a slightly alkaline solution with ethanol or acetone. It has a greyish-white colour. Colloidal solutions in water are milky, and bluish when viewed against the light due to the Tyndall ...
For superficial injuries, washing (therapeutic irrigation) is important.Emergency treatments include protecting the airway, which might involve a tracheostomy.Further treatment will vary depending on the severity, but might include investigations to determine the extent of damage (bronchoscopy for the airways and endoscopy for the gastrointestinal tract), followed by treatments including ...