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In the petroleum refining and petrochemical industries, the initialism BTX refers to mixtures of benzene, toluene, and the three xylene isomers, all of which are aromatic hydrocarbons. The xylene isomers are distinguished by the designations ortho – (or o –), meta – (or m –), and para – (or p –) as indicated in the adjacent diagram.
As benzene is ubiquitous in gasoline and hydrocarbon fuels that are in use everywhere, human exposure to benzene is a global health problem. Benzene targets the liver, kidney, lung, heart and brain and can cause DNA strand breaks and chromosomal damage, hence is teratogenic and mutagenic. Benzene causes cancer in animals including humans.
Several entrainers can be used for this specific process: benzene, pentane, cyclohexane, hexane, heptane, isooctane, acetone, and diethyl ether are all options as the mixture. [2] Of these benzene and cyclohexane have been used the most extensively, but since the identification of benzene as a carcinogen, toluene is used instead. [citation needed]
Diethylbenzenes arise as side-products of the alkylation of benzene with ethylene, which can be described as two steps. The first step is the industrial route to ethylbenzene, which is produced on a large scale as a precursor to styrene. C 6 H 6 + C 2 H 4 → C 6 H 5 C 2 H 5. The diethylbenzene is an inadvertent side product. C 6 H 5 C 2 H 5 ...
Heteroarenes are aromatic compounds, where at least one methine or vinylene (-C= or -CH=CH-) group is replaced by a heteroatom: oxygen, nitrogen, or sulfur. [3] Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one ...
The DETAL process involving dehydrogenation of n-paraffins to olefins, and subsequent reaction with benzene using a fixed bed catalyst. This is newer technology and has several of the stages depicted in the HF/n-paraffins process, but it is principally different in the benzene alkylation step, during which a solid-state catalyst is employed.
Ethylbenzene is an organic compound with the formula C 6 H 5 CH 2 CH 3.It is a highly flammable, colorless liquid with an odor similar to that of gasoline.This monocyclic aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene, the precursor to polystyrene, a common plastic material.
It is produced by methylation of other methylated benzene compounds such as p-xylene and pseudocumene. [2] C 6 H 4 (CH 3) 2 + 2 CH 3 Cl → C 6 H 2 (CH 3) 4 + 2 HCl. In industry, a mixture of xylenes and trimethylbenzenes is alkylated with methanol. Durene can be separated from its isomers by selective crystallization, exploiting its high ...