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The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5. This highly alkaline environment is one in which the steel rebar is passivated and is protected from corrosion. According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5. [1]
English: Phase Diagram for the Calcite and Aragonite System. Date: 10 April 2024: ... Phase Diagram for the CaCO3 Aragonite-Calcite system. Items portrayed in this ...
At atmospheric partial pressure of CO 2, dissolved CO 2 concentration is 1.2 × 10 −5 moles per liter. The equation before that fixes the concentration of H 2 CO 3 as a function of CO 2 concentration. For [CO 2] = 1.2 × 10 −5, it results in [H 2 CO 3] = 2.0 × 10 −8 moles per liter. When [H 2 CO 3] is known, the remaining three equations ...
The reaction may otherwise involve the functional groups of the molecule, and is a versatile class of reactions that can occur in acidic or basic conditions or in the presence of a catalyst. This class of reactions is a vital part of life as it is essential to the formation of peptide bonds between amino acids and to the biosynthesis of fatty ...
An ICE table or RICE box or RICE chart is a tabular system of keeping track of changing concentrations in an equilibrium reaction. ICE stands for initial, change, equilibrium. It is used in chemistry to keep track of the changes in amount of substance of the reactants and also organize a set of conditions that one wants to solve with. [1]
The alkali–carbonate reaction is an alteration process first suspected in the 1950s in Canada for the degradation of concrete containing dolomite aggregates. [ 1 ] [ 2 ] Alkali from the cement might react with the dolomite crystals present in the aggregate inducing the production of brucite , (MgOH) 2 , and calcite (CaCO 3 ).
In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H +) donor and the base is the proton acceptor. Typical reactions catalyzed by proton transfer are esterifications and aldol reactions.
The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.