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Chirality (/ k aɪ ˈ r æ l ɪ t i /) is a property of asymmetry important in several branches of science. The word chirality is derived from the Greek χείρ (kheir), "hand", a familiar chiral object. An object or a system is chiral if it is distinguishable from its mirror image; that is, it cannot be superposed (not to be confused with ...
An achiral molecule having chiral conformations could theoretically form a mixture of right-handed and left-handed crystals, as often happens with racemic mixtures of chiral molecules (see Chiral resolution#Spontaneous resolution and related specialized techniques), or as when achiral liquid silicon dioxide is cooled to the point of becoming ...
Chirality can be defined in two or three dimensions. It can be an intrinsic property of an object, such as a molecule, crystal or metamaterial. It can also arise from the relative position and orientation of different components, such as the propagation direction of a beam of light relative to the structure of an achiral material.
In chemistry, absolute configuration refers to the spatial arrangement of atoms within a molecular entity (or group) that is chiral, and its resultant stereochemical description. [1] Absolute configuration is typically relevant in organic molecules where carbon is bonded to four different substituents .
An achiral environment does not differentiate the molecular twins whereas a chiral environment does distinguish the left-handed version from the right-handed version. Human body, a classic bio-environment, is inherently handed as it is filled with chiral discriminators like amino acids, enzymes, carbohydrates, lipids, nucleic acids, etc.
In stereochemistry, prochiral molecules are those that can be converted from achiral to chiral in a single step. [1] [2] An achiral species which can be converted to a chiral in two steps is called proprochiral. [2] If two identical substituents are attached to an sp 3-hybridized atom, the descriptors pro-R and pro-S are used to distinguish ...
Homochirality is a uniformity of chirality, or handedness.Objects are chiral when they cannot be superposed on their mirror images. For example, the left and right hands of a human are approximately mirror images of each other but are not their own mirror images, so they are chiral.
Organic Chemistry Portal corey-bakshi-shibata-reduction The Corey–Itsuno reduction , also known as the Corey–Bakshi–Shibata (CBS) reduction , is a chemical reaction in which a prochiral ketone is enantioselectively reduced to produce the corresponding chiral , non-racemic alcohol.