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Photochemical internalization (PCI) is a drug and gene therapy delivery method originally developed to improve the release of macromolecules and hydrophilic chemotherapeutic agents from endosomes and lysosomes to the cytosol of targeted cancer cells.
Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.
Similarly, photogeochemistry may also include photochemical reactions of naturally occurring materials that are not touched by sunlight, if there is the possibility that these materials may become exposed (e.g. deep soil layers uncovered by mining).
It is important to differentiate photosensitizers from other photochemical interactions including, but not limited to, photoinitiators, photocatalysts, photoacids and photopolymerization. Photosensitizers utilize light to enact a chemical change in a substrate; after the chemical change, the photosensitizer returns to its initial state ...
Internalization may refer to: Internalization (sociology) Internalization (psychology) Internalizing disorder; Internalization (biology) Internalization theory.
A Norrish type II reaction is the photochemical intramolecular abstraction of a γ-hydrogen (a hydrogen atom three carbon positions removed from the carbonyl group) by the excited carbonyl compound to produce a 1,4-biradical as a primary photoproduct. [9] Norrish first reported the reaction in 1937. [10] Norrish type II reaction
Photobiology is the scientific study of the beneficial and harmful interactions of light (technically, non-ionizing radiation) in living organisms. [1] The field includes the study of photophysics, photochemistry, photosynthesis, photomorphogenesis, visual processing, circadian rhythms, photomovement, bioluminescence, and ultraviolet radiation effects.
In a reversible photochemical reaction between compounds A and B, there will therefore be a "forwards" reaction of at a rate proportional to and a "backwards" reaction of at a rate proportional to . The ratio of the rates of the forward and backwards reactions determines where the equilibrium lies, and thus the photostationary state is found at: