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Dimethylbutadiene, formally referred to as 2,3-dimethyl-1,3-butadiene, is an organic compound with the formula (CH 3) 2 C 4 H 4. It is colorless liquid which served an important role in the early history of synthetic rubber .
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In 1910, Sergey Lebedev systematically investigated thermal polymerization of three conjugated dienes (butadiene, isoprene and dimethylbutadiene), a process now recognized as a Diels-Alder self-reaction, providing a detailed analysis of the dimerization products and recognizing the importance of the conjugated system in the process. [69]
Butlerov's student V. Goryainov originally discovered neohexane in 1872 by cross-coupling of zinc ethyl with tert-butyl iodide. [5]2,2-Dimethylbutane can be synthesised by the hydroisomerisation of 2,3-dimethylbutane using an acid catalyst.
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