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Alkylation unit in a refinery, line width corresponds approximately to the mass flow (SAAU technology) The first alkylation units entered in service in 1940. In 2009 around 1,600,000 barrels per day of capacity were installed worldwide, [5] with an equal share of 800,000 barrels per day for SAAU and HFAU technologies. On the 1st January 2016 ...
Alkylation is a chemical reaction that entails transfer of an alkyl group. The alkyl group may be transferred as an alkyl carbocation , a free radical , a carbanion , or a carbene (or their equivalents).
Alkylation is the addition of alkyl groups to molecules, often by alkylating agents such as alkyl halides. Alkylating antineoplastic agents are a class of compounds that are used to treat cancer. In such case, the term alkyl is used loosely. For example, nitrogen mustards are well-known alkylating agents, but they are not simple hydrocarbons.
Isobutane is the principal feedstock in alkylation units of refineries. Using isobutane, gasoline-grade "blendstocks" are generated with high branching for good combustion characteristics. Typical products created with isobutane are 2,4-dimethylpentane and especially 2,2,4-trimethylpentane. [7]
In organic chemistry, transalkylation is a chemical reaction involving the transfer of an alkyl group from one organic compound to another. The reaction is used for the transfer of methyl and ethyl groups between benzene rings.
The members of an alkylation series have the same degree of unsaturation and number of heteroatoms (nitrogen, oxygen and sulfur) but differ in the number of CH 2 units. Members of an alkylation series have the same Kendrick mass defect. The Kendrick mass defect has also been defined as
The explosion was heard 5 miles away from the Valero refinery and rocked buildings within a mile of the plant, according to local media reports.
Monel is used in the section of alkylation units in direct contact with concentrated hydrofluoric acid. Monel offers exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point. It is perhaps the most resistant of all commonly used engineering alloys.