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The concentration of the species LH is equal to the sum of the concentrations of the two micro-species with the same chemical formula, labelled L 1 H and L 2 H. The constant K 2 is for a reaction with these two micro-species as products, so that [LH] = [L 1 H] + [L 2 H] appears in the numerator, and it follows that this macro-constant is equal ...
Knowing the analytical concentrations of reactants initially in the reaction vessel and in the burette, all analytical concentrations can be derived as a function of the volume (or mass) of titrant added. The equilibrium constants may be derived by best-fitting of the experimental data with a chemical model of the equilibrium system.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
Thus, to calculate the stoichiometry by mass, the number of molecules required for each reactant is expressed in moles and multiplied by the molar mass of each to give the mass of each reactant per mole of reaction. The mass ratios can be calculated by dividing each by the total in the whole reaction.
Quantifying mass transfer allows for design and manufacture of separation process equipment that can meet specified requirements, estimate what will happen in real life situations (chemical spill), etc. Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of ...
In that case, the specific volume would equal 0.4672 in 3 /lb. However, if the temperature is changed to 1160 °R, the specific volume of the super heated steam would have changed to 0.2765 in 3 /lb, which is a 59% overall change. Knowing the specific volumes of two or more substances allows one to find useful information for certain applications.