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Although a wide range of terpene structures exist, few of them are biologically significant; by contrast, diterpenoids possess a rich pharmacology and include important compounds such as retinol, phytol or taxadiene.
Terpenes are classified by the number of carbons: monoterpenes (C 10), sesquiterpenes (C 15), diterpenes (C 20), as examples. The terpene alpha-pinene is a major component of the common solvent, turpentine. The one terpene that has major applications is natural rubber (i.e., polyisoprene).
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C 10 H 16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids ...
While sometimes used interchangeably with "terpenes", terpenoids contain additional functional groups, usually containing oxygen. [1] When combined with the hydrocarbon terpenes, terpenoids comprise about 80,000 compounds. [2] They are the largest class of plant secondary metabolites, representing about 60% of known natural products. [3]
Triterpenes are a class of terpenes composed of six isoprene units with the molecular formula C 30 H 48; they may also be thought of as consisting of three terpene units. Animals, plants and fungi all produce triterpenes, including squalene, the precursor to all steroids. [1] [2]
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C 15 H 24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many combinations. Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. [1]
Tetraterpenes are terpenes consisting of eight isoprene units and have the molecular formula C 40 H 64. [1] Tetraterpenoids (including many carotenoids) are tetraterpenes that have been chemically modified, as indicated by the presence of oxygen-containing functional groups.
Terpin is an expectorant, used to loosen mucus in patients with bronchitis and related conditions. It is used as the hydrate (terpin·H 2 O). It is derived from sources such as turpentine, oregano, thyme, and eucalyptus.
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