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The equation describing the relative motion is known as the swing equation, which is a non-linear second order differential equation that describes the swing of the rotor of synchronous machine. The power exchange between the mechanical rotor and the electrical grid due to the rotor swing (acceleration and deceleration) is called Inertial response.
The Hammett equation predicts the equilibrium constant or reaction rate of a reaction from a substituent constant and a reaction type constant. The Edwards equation relates the nucleophilic power to polarisability and basicity. The Marcus equation is an example of a quadratic free-energy relationship (QFER). [citation needed]
Within chemistry, a Job plot, otherwise known as the method of continuous variation or Job's method, is a method used in analytical chemistry to determine the stoichiometry of a binding event. The method is named after Paul Job and is also used in instrumental analysis and advanced chemical equilibrium texts and research articles.
A point may be local minimum when it is lower in energy compared to its surrounding only or a global minimum which is the lowest energy point on the entire potential energy surface. Saddle point represents a maximum along only one direction (that of the reaction coordinate) and is a minimum along all other directions. In other words, a saddle ...
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
An alternative to free-energy perturbation for computing potentials of mean force in chemical space is thermodynamic integration. Another alternative, which is probably more efficient, is the Bennett acceptance ratio method. Adaptations to FEP exist which attempt to apportion free-energy changes to subsections of the chemical structure. [5]
The unknown part of the equation is y(x+Δx), which can be found if we have the data for the initial values. Runge-Kutta methods → it is more accurate than the Euler method. In this method, an initial condition is required: y = y 0 at x = x 0. The problem is to find the value of y when x = x 0 + h, where h is a given constant.
The smaller mass, labelled m, is allowed to swing freely whereas the larger mass, M, can only move up and down. Assume the pivots to be points. The swinging Atwood's machine (SAM) is a mechanism that resembles a simple Atwood's machine except that one of the masses is allowed to swing in a two-dimensional plane, producing a dynamical system ...