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An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula . For example, a solution of table salt , also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq) .
The factor i accounts for the number of individual particles (typically ions) formed by a compound in solution. Examples: i = 1 for sugar in water; i = 1.9 for sodium chloride in water, due to the near full dissociation of NaCl into Na + and Cl − (often simplified as 2)
where μ is the electric dipole moment of the effectively polarized water molecule (2.35 D for the SPC/E model), μ 0 is the dipole moment of an isolated water molecule (1.85 D from experiment), and α i is an isotropic polarizability constant, with a value of 1.608 × 10 −40 F·m 2. Since the charges in the model are constant, this ...
For example, if there are 10 grams of salt (the solute) dissolved in 1 litre of water (the solvent), this solution has a certain salt concentration . If one adds 1 litre of water to this solution, the salt concentration is reduced. The diluted solution still contains 10 grams of salt (0.171 moles of NaCl).
For example, if you add sodium chloride to water, the salt will dissociate into the ions sodium(+aq) and chloride(-aq). The equilibrium constant for this dissociation can be predicted by the change in Gibbs energy of this reaction. The Born equation is used to estimate Gibbs free energy of solvation of a gaseous ion.
The ionic strength of a solution is a measure of the concentration of ions in that solution. Ionic compounds, when dissolved in water, dissociate into ions. The total electrolyte concentration in solution will affect important properties such as the dissociation constant or the solubility of different salts. One of the main characteristics of a ...
The very ambiguous terms percent solution and percentage solutions with no other qualifiers continue to occasionally be encountered. In thermal engineering, vapor quality is used for the mass fraction of vapor in the steam. In alloys, especially those of noble metals, the term fineness is used for the mass fraction of the noble metal in the alloy.
A special instance of this equation is for the case of water with a monovalent salt. [4] The Debye length equation is then: = where is the salt concentration in mol/L. These equations all require 1:1 salt concentration cases, but if ions that have higher valence are present, the following case is used. [4]