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Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid: Zn + 2 HNO 3 → Zn(NO 3) 2 + H 2 ZnO + 2 HNO 3 → Zn(NO 3) 2 + H 2 O. These reactions are accompanied by the hydration of the zinc nitrate. The anhydrous salt arises by the reaction of anhydrous zinc chloride with nitrogen dioxide: [1]
Zinc nitride reacts violently with water to form ammonia and zinc oxide. [3] [4] Zn 3 N 2 + 3 H 2 O → 3 ZnO + 2 NH 3. Zinc nitride reacts with lithium (produced in an electrochemical cell) by insertion. The initial reaction is the irreversible conversion into LiZn in a matrix of beta-Li 3 N. These products then can be converted reversibly and ...
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
The Bunsen cell generates about 1.9 volts which arises from the following reaction: [1]. Zn + H 2 SO 4 + 2 HNO 3 ⇌ ZnSO 4 + 2 H 2 O + 2 NO 2 (g). According to the reaction above, when 1 mole (or part) each of zinc and sulfuric acid react with 2 moles (or parts) of nitric acid, the resultant products formed are, 1 mole (or part) of zinc sulfate and 2 moles (or parts) each of water and ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The reaction produces a primary, secondary, or tertiary alcohol via a 1,2-addition. The Barbier reaction is advantageous because it is a one-pot process: the organozinc reagent is generated in the presence of the carbonyl substrate. Organozinc reagents are also less water sensitive, thus this reaction can be conducted in water.