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Like pH, redox potential represents how easily electrons are transferred to or from species in solution. Redox potential characterises the ability under the specific condition of a chemical species to lose or gain electrons instead of the amount of electrons available for oxidation or reduction. The notion of pe is used with Pourbaix diagrams.
The values below are standard apparent reduction potentials (E°') for electro-biochemical half-reactions measured at 25 °C, 1 atmosphere and a pH of 7 in aqueous solution. [1] [2] The actual physiological potential depends on the ratio of the reduced (Red) and oxidized (Ox) forms according to the Nernst equation and the thermal voltage.
Oxidizing agent – Chemical compound used to oxidize another substance in a chemical reaction; Redox – Chemical reaction in which oxidation states of atoms are changed; Reducing equivalent – Chemical reaction in which oxidation states of atoms are changed; Salt-free reduction
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.
For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H + ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH − ...
Redox (/ ˈ r ɛ d ɒ k s / RED-oks, / ˈ r iː d ɒ k s / REE-doks, reduction–oxidation [2] or oxidation–reduction [3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4] Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
Both the oxidation and reduction steps are pH dependent. Figure 1 shows the standard potentials at pH 0 (strongly acidic) as referenced to the normal hydrogen electrode (NHE). 2 half reactions (at pH = 0) Oxidation 2H 2 O → 4H + + 4e − + O 2 E° = +1.23 V vs. NHE Reduction 4H + + 4e − → 2H 2 E° = 0.00 V vs. NHE
In order to flatten the steep learning curve aqion provides an introduction to fundamental water-related topics in form of a "chemical pocket calculator". Second. The program mediates between two terminological concepts: The calculations are performed in the "scientific realm" of thermodynamics (activities, speciation, log K values, ionic ...