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In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system. To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantum numbers includes the principal, azimuthal, magnetic, and spin quantum numbers. To describe other ...
The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom.So while the word symbol suggests otherwise, it represents an actual value of a physical quantity.
Each orbital in an atom is characterized by a set of values of three quantum numbers n, ℓ, and m ℓ, which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis (magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally ...
In atomic physics, a magnetic quantum number is a quantum number used to distinguish quantum states of an electron or other particle according to its angular momentum along a given axis in space. The orbital magnetic quantum number ( m l or m [ a ] ) distinguishes the orbitals available within a given subshell of an atom.
The classical definition of angular momentum is =.The quantum-mechanical counterparts of these objects share the same relationship: = where r is the quantum position operator, p is the quantum momentum operator, × is cross product, and L is the orbital angular momentum operator.
The triplet consists of three states with spin components +1, 0 and –1 along the direction of the total orbital angular momentum, which is also 1 as indicated by the letter P. The total angular momentum quantum number J can vary from L+S = 2 to L–S = 0 in integer steps, so that J = 2, 1 or 0. [1] [2]
j = total angular momentum quantum number; m j = total angular momentum magnetic quantum number; Spin: ...