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Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s 2 2s 2 2p 6 3s 1, as deduced from the Aufbau principle (see below). The first excited state is obtained by promoting a 3s electron to the 3p subshell, to obtain the 1s 2 2s 2 2p 6 3p 1 configuration, abbreviated as the 3p level ...
Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
LS coupling is for a parent ion and J 1 L 2 coupling is for a coupling of the parent ion and the excited electron. The parent ion is an unexcited part of the atom. For example, in Ar atom excited from a ground state ...3p 6 to an excited state ...3p 5 4p in electronic configuration, 3p 5 is for the parent ion while 4p is for the excited ...
When that electron is promoted to an e g orbital, it is excited to the 2 E g state energy, +6Dq. This is in accordance with the single absorption band in a UV-vis experiment. This is in accordance with the single absorption band in a UV-vis experiment.
An asterisk is commonly used to designate an excited state. An electron transition in a molecule's bond from a ground state to an excited state may have a designation such as σ → σ*, π → π*, or n → π* meaning excitation of an electron from a σ bonding to a σ antibonding orbital, from a π bonding to a π antibonding orbital, or ...
Energy levels for an electron in an atom: ground state and excited states. After absorbing energy , an electron may jump from the ground state to a higher-energy excited state. The ground state of a quantum-mechanical system is its stationary state of lowest energy ; the energy of the ground state is known as the zero-point energy of the system.
As an example, consider the ground state of silicon.The electron configuration of Si is 1s 2 2s 2 2p 6 3s 2 3p 2 (see spectroscopic notation).We need to consider only the outer 3p 2 electrons, for which it can be shown (see term symbols) that the possible terms allowed by the Pauli exclusion principle are 1 D , 3 P , and 1 S.
In the low temperature approximation, the molecule starts out in the v = 0 vibrational level of the ground electronic state and upon absorbing a photon of the necessary energy, makes a transition to the excited electronic state. The electron configuration of the new state may result in a shift of the equilibrium position of the nuclei ...