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For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
In microeconomics, a production–possibility frontier (PPF), production possibility curve (PPC), or production possibility boundary (PPB) is a graphical representation showing all the possible options of output for two that can be produced using all factors of production, where the given resources are fully and efficiently utilized per unit time.
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...
The reversible reaction 2NO 2 (g) ⇌ N 2 O 4 (g) is exothermic, so the equilibrium position can be shifted by changing the temperature. When heat is removed and the temperature decreases, the reaction shifts to the right and the flask turns colorless due to an increase in N 2 O 4. This demonstrates Le Chatelier's principle: the equilibrium ...
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
The equation can be used to fit (regress) discrete values of the shift factor a T vs. temperature. Here, values of shift factor a T are obtained by horizontal shift log(a T) of creep compliance data plotted vs. time or frequency in double logarithmic scale so that a data set obtained experimentally at temperature T superposes with the data set ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
A few different types of equilibrium are listed below. Thermal equilibrium: When the temperature throughout a system is uniform, the system is in thermal equilibrium. Mechanical equilibrium: If at every point within a given system there is no change in pressure with time, and there is no movement of material, the system is in mechanical ...