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The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
Tin(II) chloride dissolves in less than its own mass of water. Dilute solutions are subject to hydrolysis, yielding an insoluble basic salt: SnCl 2 + H 2 O ⇌ Sn(OH)Cl + HCl. Hydrolysis is prevented in the presence of hydrochloric acid, typically of the same or greater molarity as the
Condensation reactions likely played major roles in the synthesis of the first biotic molecules including early peptides and nucleic acids. In fact, condensation reactions would be required at multiple steps in RNA oligomerization: the condensation of nucleobases and sugars, nucleoside phosphorylation, and nucleotide polymerization. [6]
Its dehydration yields benzonitrile. It can be hydrolyzed to regenerate benzaldehyde. [5] It reacts with N-chlorosuccinimide in DMF to form benzohydroximoyl chloride, in which chlorine replaces hydrogen on the carbon attached to the nitrogen in benzaldehyde oxime. [6]
Peptide bond formation via dehydration reaction. When two amino acids form a dipeptide through a peptide bond, [1] it is a type of condensation reaction. [2] In this kind of condensation, two amino acids approach each other, with the non-side chain (C1) carboxylic acid moiety of one coming near the non-side chain (N2) amino moiety of the other.
Dehydration may be accompanied by decarboxylation when an activated carboxyl group is present. The aldol addition product can be dehydrated via two mechanisms; a strong base like potassium t -butoxide , potassium hydroxide or sodium hydride deprotonates the product to an enolate , which eliminates via the E1cB mechanism , [ 9 ] [ 10 ] while ...
A Proton Gradient Powers the Synthesis of ATP". Biochemistry (5th ed.). W. H. Freeman. A set of experiments aiming to test some tenets of the chemiosmotic theory – Ogawa S, Lee TM (August 1984). "The relation between the internal phosphorylation potential and the proton motive force in mitochondria during ATP synthesis and hydrolysis".
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