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In lay terms, the stoichiometric coefficient of any given component is the number of molecules and/or formula units that participate in the reaction as written. A related concept is the stoichiometric number (using IUPAC nomenclature), wherein the stoichiometric coefficient is multiplied by +1 for all products and by −1 for all reactants.
Partition coefficient (K D) - The ratio of concentrations of a compound in two phases of a mixture of two immiscible solvents at equilibrium. Hall coefficient (electrical physics) - Relates a magnetic field applied to an element to the voltage created, the amount of current and the element thickness. It is a characteristic of the material from ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
[1] [2] At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free energy is at a minimum. [3] [4] [5] In a system in diffusion equilibrium, the chemical potential of any chemical species is uniformly the same everywhere throughout the system. [6]
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
where denotes the number of moles of the reactant or product and is the stoichiometric number [4] of the reactant or product. Although less common, we see from this expression that since the stoichiometric number can either be considered to be dimensionless or to have units of moles, conversely the extent of reaction can either be considered to ...