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Solar cell output voltage for two light-induced currents I L expressed as a ratio to the reverse saturation current I 0 [52] and using a fixed ideality factor m of 2. [53] Their emf is the voltage at their y-axis intercept. Solving the illuminated diode's above simplified current–voltage relationship for output voltage yields:
Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".
The "international volt" was defined in 1893 as 1 ⁄ 1.434 of the emf of a Clark cell. This definition was abandoned in 1908 in favor of a definition based on the ...
The emf of the cell at zero current is the maximum possible emf. It can be used to calculate the maximum possible electrical energy that could be obtained from a chemical reaction . This energy is referred to as electrical work and is expressed by the following equation:
Some cells use different electrolytes for each half-cell; then a separator is used to prevent mixing of the electrolytes while allowing ions to flow between half-cells to complete the electrical circuit. Each half-cell has an electromotive force (emf, measured in volts) relative to a standard.
The emf generated by Faraday's law of induction due to relative movement of a circuit and a magnetic field is the phenomenon underlying electrical generators. When a permanent magnet is moved relative to a conductor, or vice versa, an electromotive force is created.
In electrochemistry, electrode potential is the voltage of a galvanic cell built from a standard reference electrode and another electrode to be characterized. [1] By convention, the reference electrode is the standard hydrogen electrode (SHE).
Therefore, emf is expressed as = (+) where is emf and v is the unit charge velocity. In a macroscopic view, for charges on a segment of the loop, v consists of two components in average; one is the velocity of the charge along the segment v t , and the other is the velocity of the segment v l (the loop is deformed or moved).