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ASTM C1293: "Test Method for Concrete Aggregates by Determination of Length Change of Concrete Due to Alkali-Silica Reaction". It is a long-term confirmation test (1 or 2 years) at 38 °C in a water-saturated moist atmosphere (inside a thermostated oven) with concrete prisms containing the aggregates to be characterised mixed with a high-alkali ...
Phenolphthalein's pH sensitivity is exploited in other applications: concrete has naturally high pH due to the calcium hydroxide formed when Portland cement reacts with water. As the concrete reacts with carbon dioxide in the atmosphere, pH decreases to 8.5–9. When a 1% phenolphthalein solution is applied to normal concrete, it turns bright pink.
Concrete carbonation can be visually revealed by applying a phenolphthalein solution over the fresh surface of a concrete samples (concrete core, prism, freshly fractured bar). Phenolphthalein is a pH indicator , whose color turns from colorless at pH < 8.5 to pink-fuchsia at pH > 9.5.
This process is often irreversible. Sufficient amount of free calcium ion and a high pH of 12 and above is needed to initiate and maintain the pozzolanic reaction. [2] This is because at a pH of around 12, the solubility of silicon and aluminium ions is high enough to support the pozzolanic reaction.
A fairly well-defined reaction front can often be observed in thin sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and the microstructure of concrete are modified. These changes may vary in type or severity but commonly include: Extensive cracking; Expansion
Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water (including rainwater). Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any ...
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The effect of the water-to-cement (w/c) ratio onto the mechanical strength of concrete was first studied by René Féret (1892) in France, and then by Duff A. Abrams (1918) (inventor of the concrete slump test) in the USA, and by Jean Bolomey (1929) in Switzerland.
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