Search results
Results from the WOW.Com Content Network
These two examples show that an electrical potential and a chemical potential can both give the same result: A redistribution of the chemical species. Therefore, it makes sense to combine them into a single "potential", the electrochemical potential , which can directly give the net redistribution taking both into account.
The phrase "chemical potential" sometimes means "total chemical potential", but that is not universal. [13] In some fields, in particular electrochemistry, semiconductor physics, and solid-state physics, the term "chemical potential" means internal chemical potential, while the term electrochemical potential is used to mean total chemical ...
The pseudopotential is an attempt to replace the complicated effects of the motion of the core (i.e. non-valence) electrons of an atom and its nucleus with an effective potential, or pseudopotential, so that the Schrödinger equation contains a modified effective potential term instead of the Coulombic potential term for core electrons normally found in the Schrödinger equation.
At a real surface the potential is influenced by image charges and the formation of surface dipoles and it rather looks as indicated by the dashed line. Given the potential in Figure 1, it can be shown that the one-dimensional single-electron Schrödinger equation gives two qualitatively different types of solutions. [4]
When a voltmeter is used to measure an electronic device, it does not quite measure the pure electric potential (also called Galvani potential).Instead, it measures the electrochemical potential, also called "fermi level difference", which is the total free energy difference per electron, including not only its electric potential energy but also all other forces and influences on the electron ...
The chemical potential μ is, by definition, the energy of adding an extra electron to the fluid. This energy may be decomposed into a kinetic energy T part and the potential energy − eφ part. Since the chemical potential is kept constant, Δ μ = Δ T − e Δ ϕ = 0. {\displaystyle \Delta \mu =\Delta T-e\Delta \phi =0.}
An example is the London-Eyring-Polanyi-Sato potential [2] [3] [4] for the system H + H 2 as a function of the three H-H distances. For more complicated systems, calculation of the energy of a particular arrangement of atoms is often too computationally expensive for large scale representations of the surface to be feasible.
[2] [3] Other theoretical concepts that use electron affinity include electronic chemical potential and chemical hardness. Another example, a molecule or atom that has a more positive value of electron affinity than another is often called an electron acceptor and the less positive an electron donor. Together they may undergo charge-transfer ...