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Sodium chlorate can be used with hydrochloric acid (or also sulfuric acid and sodium chloride, the reaction of which generates HCl) to chlorinate aromatic compounds without the use of organic solvents. In this case its function is to oxidize the HCl to obtain either HOCl or Cl 2 (depending upon the pH) in-situ which are the active chlorinating ...
Hypochlorous acid is an inorganic compound with the chemical formula Cl O H, also written as HClO, HOCl, or ClHO. [2] [3] Its structure is H−O−Cl.It is an acid that forms when chlorine dissolves in water, and itself partially dissociates, forming a hypochlorite anion, ClO −.
This depends on factors such as solution temperature, the amount of time the Cl 2 molecule is in contact with the solution, and concentration of NaOH. Likewise, as hypochlorite increases in concentration, chlorates are produced from them: 3 NaClO → NaClO 3 + 2 NaCl. This reaction is accelerated at temperatures above about 60 °C.
3 NaOCl(aq) → 2 NaCl(aq) + NaClO 3 (aq) This reaction is exploited in the industrial production of sodium chlorate. An alternative decomposition of hypochlorite produces oxygen instead: 2 OCl − → 2 Cl − + O 2. In hot sodium hypochlorite solutions, this reaction competes with chlorate formation, yielding sodium chloride and oxygen gas: [25]
Small amounts of hydrogen chloride for laboratory use can be generated in an HCl generator by dehydrating hydrochloric acid with either sulfuric acid or anhydrous calcium chloride. Alternatively, HCl can be generated by the reaction of sulfuric acid with sodium chloride: [17] NaCl + H 2 SO 4 → NaHSO 4 + HCl↑. This reaction occurs at room ...
Sodium bisulfate is produced as an intermediate in the Mannheim process, an industrial process involving the reaction of sodium chloride and sulfuric acid: [1] NaCl + H 2 SO 4 → HCl + NaHSO 4. The process for the formation of sodium bisulfate is highly exothermic. The liquid sodium bisulfate is sprayed and cooled so that it forms a solid bead.
This is an accepted version of this page This is the latest accepted revision, reviewed on 29 September 2024. Not to be confused with sodium chloride. Sodium chlorite The sodium cation Space-filling model of the chlorite anion Names IUPAC name Sodium chlorite Other names Chlorous acid, sodium salt Textone Identifiers CAS Number 7758-19-2 Y 49658-21-1 (trihydrate) Y 3D model (JSmol) Interactive ...
The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2). Cl 2 + 2 NaOH → NaCl + NaClO + H 2 O 2 Cl 2 + 2 Ca(OH) 2 → CaCl 2 + Ca(ClO) 2 + 2 H 2 O