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Sulfuric acid is a very important commodity chemical; a country's sulfuric acid production is a good indicator of its industrial strength. [9] Many methods for its production are known, including the contact process, the wet sulfuric acid process, and the lead chamber process. [10] Sulfuric acid is also a key substance in the chemical industry.
These gases react with water and air to form sulfuric acid (H₂SO₄) and nitric acid (HNO₃). [ 8 ] [ 10 ] [ 11 ] Similar to sulfuric acid, nitric acid also decrease the pH level by dissociates into hydrogen ions (H⁺) and nitrate ions (NO₃⁻).
Sulfuric(IV) acid (United Kingdom spelling: sulphuric(IV) acid), also known as sulfurous (UK: sulphurous) acid and thionic acid, [citation needed] is the chemical compound with the formula H 2 SO 3. Raman spectra of solutions of sulfur dioxide in water show only signals due to the SO 2 molecule and the bisulfite ion, HSO − 3 . [ 2 ]
The higher sulfuric acid content of rain also may not release as much Al 3+ from soils as does nitric acid, in part due to the retention (adsorption) of SO 4 2-by soils. This process releases OH − into soil solution and buffers the pH decrease caused by the added H + from both acids. The forest floor organic soil horizons (layers) that are ...
The pH of an alkaline soil can be reduced by adding acidifying agents or acidic organic materials. Elemental sulfur (90–99% S) has been used at application rates of 300–500 kg/ha (270–450 lb/acre) – it slowly oxidises in the soil to form sulfuric acid.
The Hammett acidity function (H 0) is a measure of acidity that is used for very concentrated solutions of strong acids, including superacids.It was proposed by the physical organic chemist Louis Plack Hammett [1] [2] and is the best-known acidity function used to extend the measure of Brønsted–Lowry acidity beyond the dilute aqueous solutions for which the pH scale is useful.
The measurement of pH can become difficult at extremely acidic or alkaline conditions, such as below pH 2.5 (ca. 0.003 mol/dm 3 acid) or above pH 10.5 (above ca. 0.0003 mol/dm 3 alkaline). This is due to the breakdown of the Nernst equation in such conditions when using a glass electrode.
A typical mixture is 3 parts of concentrated sulfuric acid and 1 part of 30 wt. % hydrogen peroxide solution; [1] other protocols may use a 4:1 or even 7:1 mixture. A closely related mixture, sometimes called "base piranha", is a 5:1:1 mixture of water, ammonia solution ( NH 4 OH , or NH 3 (aq) ), and 30% hydrogen peroxide.
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