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In atomic physics, the Bohr model or Rutherford–Bohr model was the first successful model of the atom. Developed from 1911 to 1918 by Niels Bohr and building on Ernest Rutherford 's nuclear model , it supplanted the plum pudding model of J J Thomson only to be replaced by the quantum atomic model in the 1920s.
In contrast to the Bohr model of chemical bonding, it turned out that the electron cloud mainly concentrates on the line between the nuclei, providing a Coulomb attraction between them. For many-electron atoms, the valence bond theory, laid down in 1927 by Walter Heitler and Fritz London, was a successful approximation.
Rutherford's model, being supported primarily by scattering data unfamiliar to many scientists, did not catch on until Niels Bohr joined Rutherford's lab and developed a new model for the electrons. [54]: 304 Rutherford model predicted that the scattering of alpha particles would be proportional to the square of the atomic charge.
In 1913, Niels Bohr proposed a model of the atom, giving the arrangement of electrons in their sequential orbits. At that time, Bohr allowed the capacity of the inner orbit of the atom to increase to eight electrons as the atoms got larger, and "in the scheme given below the number of electrons in this [outer] ring is arbitrary put equal to the normal valency of the corresponding element".
Atomicity is the total number of atoms present in a molecule of an element. For example, each molecule of oxygen (O 2) is composed of two oxygen atoms. Therefore, the atomicity of oxygen is 2. [1] In older contexts, atomicity is sometimes equivalent to valency. Some authors also use the term to refer to the maximum number of valencies observed ...
Bohr's original configurations would seem strange to a present-day chemist: sulfur was given as 2.4.4.6 instead of 1s 2 2s 2 2p 6 3s 2 3p 4 (2.8.6). Bohr used 4 and 6 following Alfred Werner's 1893 paper. In fact, the chemists accepted the concept of atoms long before the physicists. Langmuir began his paper referenced above by saying,
The valence is the combining capacity of an atom of a given element, determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1.
Here [Ne] refers to the core electrons which are the same as for the element neon (Ne), the last noble gas before phosphorus in the periodic table. The valence electrons (here 3s 2 3p 3) are written explicitly for all atoms. Electron configurations of elements beyond hassium (element 108) have never been measured; predictions are used below.