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Ethane-1,2-dithiol, also known as EDT, [1] is a colorless liquid with the formula C 2 H 4 2. It has a very characteristic odor which is compared by many people to rotten cabbage . It is a common building block in organic synthesis and an excellent ligand for metal ions.
Their stability contrasts with the rarity of geminal diols. Examples include methanedithiol, ethane-1,1-dithiol, and cyclohexane-1,1-dithiol. Upon heating, gem-dithiols often release hydrogen sulfide, giving the transient thioketone or thial, which typically convert to oligomers. [1]
In the presence of oxygen, ethane-1,1-dithiol is converted to cis/trans-3,6-dimethyl-1,2,4,5-tetrathiane which has a rubbery aroma. This molecule has a ring with four sulfur atoms and two carbons, two ethane-1,1-dithiol molecules become linked at their sulfur atoms with the loss of hydrogen. [ 11 ]
Dithioacetals generated from aldehydes and either 1,2-ethanedithiol or 1,3-propanedithiol are especially common among this class of molecules for use in organic synthesis. [ 2 ] The carbonyl carbon of an aldehyde is electrophilic and therefore susceptible to attack by nucleophiles , whereas the analogous central carbon of a dithioacetal is not ...
Ethanedithiol may refer to: 1,1-Ethanedithiol; 1,2-Ethanedithiol; See also. Methanedithiol This page was last edited on 18 July 2024, at 03:17 (UTC). Text is ...
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Ethanethiol, commonly known as ethyl mercaptan, is an organosulfur compound with the formula CH 3 CH 2 SH. [5] It is a colorless liquid with a distinct odor. Abbreviated EtSH, it consists of an ethyl group (Et), CH 3 CH 2, attached to a thiol group, SH. Its structure parallels that of ethanol, but with sulfur in place of oxygen. The odor of ...
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