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Iron is a chemical element; it has the symbol Fe (from Latin ferrum 'iron') and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table . It is, by mass, the most common element on Earth , forming much of Earth's outer and inner core .
Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [2]
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Iron oxide pigment. The brown color indicates that iron is at the oxidation state +3. Green and reddish brown stains on a limestone core sample, respectively corresponding to oxides/hydroxides of Fe 2+ and Fe 3+. Iron oxides feature as ferrous or ferric or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are ...
Iron(II,III) oxide, or black iron oxide, is the chemical compound with formula Fe 3 O 4.It occurs in nature as the mineral magnetite.It is one of a number of iron oxides, the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe 2 O 3) which also occurs naturally as the mineral hematite.
Group 8 is a group (column) of chemical elements in the periodic table. It consists of iron (Fe), ruthenium (Ru), osmium (Os) and hassium (Hs). [1] "Group 8" is the modern standard designation for this group, adopted by the IUPAC in 1990. [1] It should not be confused with "group VIIIA" in the CAS system, which is group 18 (current IUPAC), the ...
When metallic iron (oxidation state 0) is placed in a solution of hydrochloric acid, iron(II) chloride is formed, with release of hydrogen gas, by the reaction Fe 0 + 2 H + → Fe 2+ + H 2. Iron(II) is oxidized by hydrogen peroxide to iron(III), forming a hydroxyl radical and a hydroxide ion in the process. This is the Fenton reaction.
Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite.It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.