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In analytical chemistry, the detection limit, lower limit of detection, also termed LOD for limit of detection or analytical sensitivity (not to be confused with statistical sensitivity), is the lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) with a stated confidence level (generally 99%).
A 95% confidence level does not mean that 95% of the sample data lie within the confidence interval. A 95% confidence level does not mean that there is a 95% probability of the parameter estimate from a repeat of the experiment falling within the confidence interval computed from a given experiment. [25]
However, at 95% confidence, Q = 0.455 < 0.466 = Q table 0.167 is not considered an outlier. McBane [ 1 ] notes: Dixon provided related tests intended to search for more than one outlier, but they are much less frequently used than the r 10 or Q version that is intended to eliminate a single outlier.
In the social sciences, a result may be considered statistically significant if its confidence level is of the order of a two-sigma effect (95%), while in particle physics and astrophysics, there is a convention of requiring statistical significance of a five-sigma effect (99.99994% confidence) to qualify as a discovery.
The resulting UCL will be the greatest average value that will occur for a given confidence interval and population size. In other words, ¯ being the mean of the set of observations, the probability that the mean of the distribution is inferior to UCL 1 − α is equal to the confidence level 1 − α.
Classically, a confidence distribution is defined by inverting the upper limits of a series of lower-sided confidence intervals. [15] [16] [page needed] In particular, For every α in (0, 1), let (−∞, ξ n (α)] be a 100α% lower-side confidence interval for θ, where ξ n (α) = ξ n (X n,α) is continuous and increasing in α for each sample X n.
For example, the 68% confidence limits for a one-dimensional variable belonging to a normal distribution are approximately ± one standard deviation σ from the central value x, which means that the region x ± σ will cover the true value in roughly 68% of cases. If the uncertainties are correlated then covariance must be taken into account ...
A Bland–Altman plot (difference plot) in analytical chemistry or biomedicine is a method of data plotting used in analyzing the agreement between two different assays. It is identical to a Tukey mean-difference plot, [1] the name by which it is known in other fields, but was popularised in medical statistics by J. Martin Bland and Douglas G ...