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It represents the pentahydrate of magnesium carbonate, and has the total formula MgCO 3 ·5H 2 O . [2] Landsfordite was discovered in 1888 in a coal mine in Lansford, Pennsylvania. It crystallizes in the monoclinic system (space group P2 1 /c [3]) and typically occurs as colorless to white prismatic crystals and stalactitic masses. [4]
Magnesium carbonate is ordinarily obtained by mining the mineral magnesite. Seventy percent of the world's supply is mined and prepared in China. [9] Magnesium carbonate can be prepared in laboratory by reaction between any soluble magnesium salt and sodium bicarbonate: MgCl 2 (aq) + 2 NaHCO 3 (aq) → MgCO 3 (s) + 2 NaCl(aq) + H 2 O(l) + CO 2 (g)
It is the most common cave carbonate after calcite and aragonite. [2] The mineral thermally decomposes, [5] [6] over a temperature range of approximately 220 °C to 550 °C, releasing water and carbon dioxide leaving a magnesium oxide residue. Hydromagnesite was first described in 1836 for an occurrence in Hoboken, New Jersey. [3]
Magnesium hypochlorite and magnesium chlorite are unstable compounds, they are easy to hydrolyze, the former generates basic salt Mg(OCl) 2 ·2Mg(OH) 2 and the latter generates hydroxide Mg(OH) 2; magnesium chlorate can be obtained by reacting magnesium carbonate with chloric acid and crystallizing hexahydrate from solution, which can also be ...
Artinite is a hydrated basic magnesium carbonate mineral with formula: Mg 2 (CO 3)(OH) 2 ·3H 2 O. It forms white silky monoclinic prismatic crystals that are often in radial arrays or encrustations. It has a Mohs hardness of 2.5 and a specific gravity of 2.
The fundamental difficulty to nucleate anhydrous magnesium carbonate remains when using this non-aqueous solution. Not cation dehydration, but rather the spatial configuration of carbonate anions creates the barrier in the low-temperature nucleation of magnesite. [8] Magnesite has been found in modern sediments, caves and soils.
Dypingite is a hydrated magnesium carbonate mineral with the formula: Mg 5 (CO 3) 4 (OH) 2 ·5H 2 O. Its type locality is the Dypingdal serpentine-magnesite deposit, Snarum, Norway. Synthethic dypingite is known as heavy magnesium carbonate.
Nesquehonite is a mineral of magnesium carbonate (MgCO 3).It represents the trihydrate of magnesium carbonate, and has the total formula MgCO 3 ·3H 2 O . [2] It was described in 1890 by F. A. Genth and S. L. Penfield and is named after its type locality of Nesquehoning, Pennsylvania, where it was sampled from a coal mine. [2]