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The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 101.325 kPa (1 atm). Since 1982, STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 100 kPa (1 bar). Conversions between each volume flow metric are calculated using the following formulas: Prior to 1982,
In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely, multiply by 0.001. Specific volume is inversely proportional to density. If the density of a substance doubles, its specific volume, as expressed in the same base units, is cut in half.
One way to write the van der Waals equation is: [8] [9] [10] = where is pressure, is temperature, and = / is molar volume. In addition is the Avogadro constant, is the volume, and is the number of molecules (the ratio / is a physical quantity with base unit mole (symbol mol) in the SI).
A standard cubic foot (scf) is a unit representing the amount of gas (such as natural gas) contained in a volume of one cubic foot at reference temperature and pressure conditions. It is the unit commonly used when following the customary system, a collection of standards set by the National Institute of Standards and Technology.
The standard temperature and pressure (STP) for gas varies depending on the particular code being used. [1] It is just as important to know the standard pressure as the temperature. Formerly, OPEC used 101.325 kPa (14.696 psia) but now the standard is 101.560 kPa (14.73 psia).
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where is the pressure, is the number of moles of gas, is the absolute temperature, is the gas constant, and is unit volume. For an ideal gas the compressibility factor is Z = 1 {\displaystyle Z=1} per definition.