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The adduct with diethyl ether, boron trifluoride diethyl etherate, or just boron trifluoride etherate, (BF 3 ·O(CH 2 CH 3) 2) is a conveniently handled liquid and consequently is widely encountered as a laboratory source of BF 3. [16] Another common adduct is the adduct with dimethyl sulfide (BF 3 ·S(CH 3) 2), which can be handled as a neat ...
Structure of boron trifluoride, an example of a molecule with trigonal planar geometry. In chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane. [1]
Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths , bond angles , torsional angles and any other geometrical parameters that determine the position of each atom.
However, the three hydrogen atoms are repelled by the electron lone pair in a way that the geometry is distorted to a trigonal pyramid (regular 3-sided pyramid) with bond angles of 107°. In contrast, boron trifluoride is flat, adopting a trigonal planar geometry because the boron does not have a lone pair of electrons.
For example, fluoride (F −) and boron trifluoride (BF 3) combined to give the tetrafluoroborate anion, BF 4 −. Boron trifluoride is used in the petrochemical industry as a catalyst. The halides react with water to form boric acid. [1]
Relativistic effects on the electron orbitals of superheavy elements is predicted to influence the molecular geometry of some compounds. For instance, the 6d 5/2 electrons in nihonium play an unexpectedly strong role in bonding, so NhF 3 should assume a T-shaped geometry, instead of a trigonal planar geometry like its lighter congener BF 3. [38]
Boron trifluoride is a planar molecule. It has only six electrons around the central boron atom (and thus an incomplete octet), but it readily accepts a Lewis base , forming adducts with lone-pair-containing molecules or ions such as ammonia or another fluoride ion which can donate two more electrons to complete the octet. [ 79 ]
Boron trifluoride, BF 3, a pungent colourless toxic gas; Bromotrifluoromethane, CBrF 3, (carbon monobromide trifluoride) Bromine trifluoride, BrF 3;