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Sphalerite, the more common polymorph of zinc sulfide Wurtzite, the less common polymorph of zinc sulfide. ZnS exists in two main crystalline forms. This dualism is an example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite.
Sphalerite has been found as a pseudomorph, taking the crystal structure of galena, tetrahedrite, barite and calcite. [ 13 ] [ 15 ] Sphalerite can have Spinel Law twins, where the twin axis is [111]. The chemical formula of sphalerite is (Zn,Fe)S ; the iron content generally increases with increasing formation temperature and can reach up to 40 ...
This is also known as the sphalerite structure or the Structurbericht designation B3. Pages in category "Zincblende crystal structure" The following 36 pages are in this category, out of 36 total.
Wurtzite is a zinc and iron sulfide mineral with the chemical formula (Zn,Fe)S, a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent. [5] It is trimorphous with matraite and sphalerite. [2] It occurs in hydrothermal deposits associated with sphalerite, pyrite, chalcopyrite ...
The sphalerite ore found here was presumably converted to zinc oxide via roasting, although no archaeological evidence of this has been found. Smelting is thought to have been done in sealed cylindrical clay retorts which were packed with a mixture of roasted ore, dolomite , and an organic material, perhaps cow dung , and then placed vertically ...
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There occur as many Madelung constants M i in a crystal structure as ions occupy different lattice sites. For example, for the ionic crystal NaCl, there arise two Madelung constants – one for Na and another for Cl. Since both ions, however, occupy lattice sites of the same symmetry they both are of the same magnitude and differ only by sign.
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