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Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The line segments AB and CD are perpendicular to each other. In mathematics, orthogonality is the generalization of the geometric notion of perpendicularity.Although many authors use the two terms perpendicular and orthogonal interchangeably, the term perpendicular is more specifically used for lines and planes that intersect to form a right angle, whereas orthogonal is used in generalizations ...
This constraint removes one degree of freedom from the choices of (originally) six free bond angles to leave only five choices of bond angles. (The angles θ 11 , θ 22 , θ 33 , and θ 44 are always zero and that this relationship can be modified for a different number of peripheral atoms by expanding/contracting the square matrix.)
In the context of chemistry, cis indicates that the functional groups (substituents) are on the same side of some plane, while trans conveys that they are on opposing (transverse) sides. Cis – trans isomers are stereoisomers , that is, pairs of molecules which have the same formula but whose functional groups are in different orientations in ...
For example, a right shoe is different from a left shoe, and clockwise is different from anticlockwise. See [3] for a full mathematical definition. A chiral object and its mirror image are said to be enantiomorphs. The word enantiomorph stems from the Greek ἐναντίος (enantios) 'opposite' + μορφή (morphe) 'form'. A non-chiral ...
The terms are derived from the Latin words for "left" (sinister) and "right" (dexter). Other disciplines use different terms (such as dextro-and laevo-rotary in chemistry, or clockwise and anticlockwise in physics) or simply use left and right (as in anatomy). Relative direction and chirality are distinct concepts.
The absolute value is required in above formulas, as the planes are not changed when changing all coefficient signs in one equation, or replacing one normal vector by its opposite. However the absolute values can be and should be avoided when considering the dihedral angle of two half planes whose boundaries are the same line.
An important factor in the antiperiplanar conformer is the interaction between molecular orbitals. Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar.