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In accordance with an E2 elimination the reaction with t-butyl chloride results in a KIE of 2.3. The methyl chloride reaction (only S N 2 possible) on the other hand has a KIE of 0.85 consistent with a S N 2 reaction because in this reaction type the C-H bonds tighten in the transition state. The KIE's for the ethyl (0.99) and isopropyl (1.72 ...
[A 2] Of this experiment, Albert Einstein wrote, "If the Michelson–Morley experiment had not brought us into serious embarrassment, no one would have regarded the relativity theory as a (halfway) redemption." [A 3]: 219 Michelson–Morley type experiments have been repeated many times with steadily increasing sensitivity.
A 1,2-Wittig rearrangement is a categorization of chemical reactions in organic chemistry, and consists of a 1,2-rearrangement of an ether with an alkyllithium compound. [1] The reaction is named for Nobel Prize winning chemist Georg Wittig. [2] [3] The intermediate is an alkoxy lithium salt, and the final product an alcohol.
According to ancient and medieval science, aether (/ ˈ iː θ ər /, alternative spellings include æther, aither, and ether), also known as the fifth element or quintessence, is the material that fills the region of the universe beyond the terrestrial sphere. [1]
A typical example of the first group is the solvent and anaesthetic diethyl ether, commonly referred to simply as "ether" (CH 3 −CH 2 −O−CH 2 −CH 3). Ethers are common in organic chemistry and even more prevalent in biochemistry , as they are common linkages in carbohydrates and lignin .
Ethyl 2-methylacetoacetate and campholenic aldehyde react in an Aldol condensation. [15] The synthetic procedure [16] is typical for this type of reaction. In the process, in addition to water, an equivalent of ethanol and carbon dioxide are lost in decarboxylation.
Alkenes can be made from alcohols by dehydration. This conversion, among others, is used in converting biomass to liquid fuels. [2] The conversion of ethanol to ethylene is a fundamental example: [3] [4] CH 3 CH 2 OH → H 2 C=CH 2 + H 2 O. The reaction is accelerated by acid catalysts such as sulfuric acid and certain zeolites.
Elution principle of column chromatography. In analytical and organic chemistry, elution is the process of extracting one material from another by washing with a solvent: washing of loaded ion-exchange resins to remove captured ions, or eluting proteins or other biopolymers from a gel electrophoresis or chromatography column.