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Other NMR data MS; Masses of main fragments 133, 135, 170 ... Silicon tetrachloride (data page) 1 language ...
Silicon tetrachloride is prepared by the chlorination of various silicon compounds such as ferrosilicon, silicon carbide, or mixtures of silicon dioxide and carbon. The ferrosilicon route is most common. [3] In the laboratory, SiCl 4 can be prepared by treating silicon with chlorine at 600 °C (1,112 °F): [1] Si + 2 Cl 2 → SiCl 4
Silicon tetrachloride and trichlorosilane are intermediates in the production of ultrapure silicon in the semiconductor industry. Chlorosilanes obtained from crude silicon are purified by fractional distillation techniques and then reduced with hydrogen to give silicon of 99.999 999 999 % purity.
The first organosilicon compounds were reported in 1863 by Charles Friedel and James Crafts who synthesized tetraethylsilane from diethylzinc and silicon tetrachloride. [1] However, major progress in organosilicon chemistry did not occur until Frederick Kipping and his students began experimenting with diorganodichlorosilanes ( R 2 SiCl 2 ...
Purified trichlorosilane is the principal precursor to ultrapure silicon in the semiconductor industry. In water, it rapidly decomposes to produce a siloxane polymer while giving off hydrochloric acid. Because of its reactivity and wide availability, it is frequently used in the synthesis of silicon-containing organic compounds. [2]
Its use in NMR spectroscopy has been largely superseded by deuterated solvents (mainly deuterochloroform). The use of carbon tetrachloride in the determination of oil has been replaced by various other solvents, such as tetrachloroethylene. [26] Because it has no C–H bonds, carbon tetrachloride does not easily undergo free-radical reactions.
The rate of consumption of silicon tetrachloride is increasing due to rising demand for polysilicon around the world. Market Overview. Silicon Tetrachloride (SiClâ‚„) is a versatile chemical compound primarily used in the production of high-purity silica and optical fibers. Its applications span various high-tech industries, including ...
Tetramethylsilane is the accepted internal standard for calibrating chemical shift for 1 H, 13 C and 29 Si NMR spectroscopy in organic solvents (where TMS is soluble). In water, where it is not soluble, sodium salts of DSS, 2,2-dimethyl-2-silapentane-5-sulfonate, are used instead.