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Insensitive nuclei enhancement by polarization transfer (INEPT) is a signal enhancement method used in NMR spectroscopy. It involves the transfer of nuclear spin polarization from spins with large Boltzmann population differences to nuclear spins of interest with lower Boltzmann population differences. [ 1 ]
The IBM2/IBM-II model treats protons and neutrons separately. Both models are restricted to nuclei with even numbers of protons and neutrons. [1]: 9 Regions of differently shaped nuclei, as predicted by the Interacting Boson Approximation [2] The model can be used to predict vibrational and rotational modes of non-spherical nuclei. [2]
When electron spin polarization deviates from its thermal equilibrium value, polarization transfers between electrons and nuclei can occur spontaneously through electron-nuclear cross relaxation or spin-state mixing among electrons and nuclei. For example, polarization transfer is spontaneous after a homolysis chemical reaction.
The nuclear Overhauser effect (NOE) is the transfer of nuclear spin polarization from one population of spin-active nuclei (e.g. 1 H, 13 C, 15 N etc.) to another via cross-relaxation.
Graphical representation of the INEPT NMR pulse sequence. INEPT is utilized often to improve 15 N resolution because it can accommodate negative gyromagnetic ratios, increases Boltzmann polarization, and decreases T 1 relaxation. [3] Insensitive nuclei enhanced by polarization transfer (INEPT) is a signal
A more specific example of this case is presented in the section Chemical Exchange Magnetization transfer. In either case, magnetization transfer techniques probe the dynamic relationship between two or more distinguishable nuclei populations, in so far as energy exchange between the populations can be induced and measured in an idealized NMR ...
Cross-polarization (CP), originally published as nuclear double resonance in the rotating frame by Hartmann and Hahn [1] is a solid-state nuclear magnetic resonance (ssNMR) technique used to transfer nuclear magnetization from different types of nuclei via heteronuclear dipolar interactions.
In nuclear physics, a beta decay transition is the change in state of an atomic nucleus undergoing beta decay.When undergoing beta decay, a nucleus emits a beta particle and a corresponding neutrino, transforming the original nuclide into one with the same mass number but differing atomic number (nuclear charge).