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General structure of a sulfide with the blue marked functional group. In organic chemistry, a sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right. Like many other sulfur-containing compounds, volatile sulfides have foul odors. [1]
Sulfide (also sulphide in British English) [2] is an inorganic anion of sulfur with the chemical formula S 2− or a compound containing one or more S 2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide.
[15] [16] The term "methyl" was derived in about 1840 by back-formation from "methylene", and was then applied to describe "methyl alcohol" (which since 1892 is called "methanol"). Methyl is the IUPAC nomenclature of organic chemistry term for an alkane (or alkyl) molecule, using the prefix "meth-" to indicate the presence of a single carbon.
The compound (C 5 H 5) 2 TiS 5 is an example of a polysulfide complex. Polysulfides are a class of chemical compounds derived from anionic chains of sulfur atoms. [1] There are two main classes of polysulfides: inorganic and organic. The inorganic polysulfides have the general formula S 2− n. These anions are the conjugate bases of ...
Allyl methyl sulfide is an organosulfur compound with the chemical formula CH 2 =CHCH 2 SCH 3. The molecule features two functional groups, an allyl (CH 2 =CHCH 2) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It is a metabolite of garlic, and "garlic breath" is attributed to its presence. [1]
Reduction of β-ketosulfoxides with aluminium amalgam gives methyl ketones (3). [10] Reaction with alkyl halides followed by elimination gives α,β-unsaturated ketones ( 4 ). β-ketosulfoxides can also be used in the Pummerer rearrangement to introduce nucleophiles alpha to a carbonyl ( 5 ).
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MTSL (S-(1-oxyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-3-yl)methyl methanesulfonothioate) is an organosulfur compound that is used as a nitroxide spin label. [1] MTSL is bifunctional, consisting of the nitroxide and the thiosulfonate ester functional groups. The nitroxide label is sterically protected, so it is relatively unreactive.