Search results
Results from the WOW.Com Content Network
The ingredient or monomer is ethylene (IUPAC name ethene), a gaseous hydrocarbon with the formula C 2 H 4, which can be viewed as a pair of methylene groups (− CH 2 −) connected to each other. Typical specifications for PE purity are <5 ppm for water, oxygen, and other alkenes contents.
In place of the monomer name used in source-based nomenclature, structure-based nomenclature uses that of the "preferred constitutional repeating unit" (CRU). [9] It can be determined as follows: A large enough part of the polymer chain is drawn to show the structural repetition.
Electrolysis of a solution containing both monomer and electrolyte. A monomer molecule will receive an electron at the cathode to become a radical anion, and a monomer molecule will give up an electron at the anode to form a radical cation (Figure 6). The radical ions then initiate free radical (and/or ionic) polymerization.
The formal thermodynamic criterion of a given monomer polymerizability is related to a sign of the free enthalpy (Gibbs free energy) of polymerization: = () where: x and y indicate monomer and polymer states, respectively ( x and/or y = l (liquid), g ( gaseous ), c ( amorphous solid ), c' ( crystalline solid ), s ( solution ));
Other monomer units, such as formaldehyde hydrates or simple aldehydes, are able to polymerize themselves at quite low temperatures (ca. −80 °C) to form trimers; [3] molecules consisting of 3 monomer units, which can cyclize to form ring cyclic structures, or undergo further reactions to form tetramers, [3] or 4 monomer-unit compounds.
LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
In polymer science, dispersion polymerization is a heterogeneous polymerization process carried out in the presence of a polymeric stabilizer in the reaction medium. . Dispersion polymerization is a type of precipitation polymerization, meaning the solvent selected as the reaction medium is a good solvent for the monomer and the initiator, but is a non-solvent for the po
Branching sometimes occurs spontaneously during synthesis of polymers; e.g., by free-radical polymerization of ethylene to form polyethylene. In fact, preventing branching to produce linear polyethylene requires special methods. Because of the way polyamides are formed, nylon would seem to be limited to unbranched, straight chains.