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The sign of the phase itself does not have physical meaning except when mixing orbitals to form molecular orbitals. Two same-sign orbitals have a constructive overlap forming a molecular orbital with the bulk of the electron density located between the two nuclei. This MO is called the bonding orbital and its energy is lower than that of the ...
Diatomic carbon (systematically named dicarbon and 1λ 2,2λ 2-ethene), is a green, gaseous inorganic chemical with the chemical formula C=C (also written [C 2] or C 2).It is kinetically unstable at ambient temperature and pressure, being removed through autopolymerisation.
bond order = number of bonding electrons - number of antibonding electrons / 2 Generally, the higher the bond order, the stronger the bond. Bond orders of one-half may be stable, as shown by the stability of H + 2 (bond length 106 pm, bond energy 269 kJ/mol) and He + 2 (bond length 108 pm, bond energy 251 kJ/mol). [8]
An MO will have σ-symmetry if the orbital is symmetric with respect to the axis joining the two nuclear centers, the internuclear axis. This means that rotation of the MO about the internuclear axis does not result in a phase change. A σ* orbital, sigma antibonding orbital, also maintains the same phase when rotated about the internuclear axis.
Theoretically predicted phase diagram of carbon, from 1989. Newer work indicates that the melting point of diamond (top-right curve) does not go above about 9000 K. [19] The allotropes of carbon include graphite, one of the softest known substances, and diamond, the hardest naturally occurring substance.
A primitive Pythagorean triple is one in which a, b and c are coprime (that is, they have no common divisor larger than 1). [1] For example, (3, 4, 5) is a primitive Pythagorean triple whereas (6, 8, 10) is not. Every Pythagorean triple can be scaled to a unique primitive Pythagorean triple by dividing (a, b, c) by their greatest common divisor ...
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For one like atom in a 1 S g state and one in a 1 P u state, the possible diatomic states are 1 Σ g +, 1 Σ u +, 1 Π g and 1 Π u. [5] The parity of an atomic term is g if the sum of the individual angular momentum is even, and u if the sum is odd.