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In organic chemistry, a vinyl group (abbr. Vi; [1] IUPAC name: ethenyl group [2]) is a functional group with the formula −CH=CH 2. It is the ethylene (IUPAC name: ethene) molecule (H 2 C=CH 2) with one fewer hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH 2 where R is any other group of atoms.
The name of CH 2 =CH 2 is therefore ethENe. For straight-chain alkenes with 4 or more carbon atoms, that name does not completely identify the compound. For those cases, and for branched acyclic alkenes, the following rules apply: Find the longest carbon chain in the molecule.
In ethene, the two carbon atoms form a σ bond by overlapping one sp 2 orbital from each carbon atom. The π bond between the carbon atoms perpendicular to the molecular plane is formed by 2p–2p overlap. Each carbon atom forms covalent C–H bonds with two hydrogens by s–sp 2 overlap, all with 120° bond angles. The hydrogen–carbon bonds ...
A bond between a hydrogen atom and an sp 2 hybridised carbon atom is about 0.6% shorter than between hydrogen and sp 3 hybridised carbon. A bond between hydrogen and sp hybridised carbon is shorter still, about 3% shorter than sp 3 C-H. This trend is illustrated by the molecular geometry of ethane, ethylene and acetylene. [citation needed]
The combustion of ethane releases 1559.7 kJ/mol, or 51.9 kJ/g, of heat, and produces carbon dioxide and water according to the chemical equation: 2 C 2 H 6 + 7 O 2 → 4 CO 2 + 6 H 2 O + 3120 kJ. Combustion may also occur without an excess of oxygen, yielding carbon monoxide, acetaldehyde, methane, methanol, and ethanol.
In the mid-19th century, the suffix -ene (an Ancient Greek root added to the end of female names meaning "daughter of") was widely used to refer to a molecule or part thereof that contained one fewer hydrogen atoms than the molecule being modified. Thus, ethylene (C 2 H 4) was the "daughter of ethyl" (C 2 H 5). The name ethylene was used in ...
In ethylene each carbon atom has three sp 2 orbitals and one p-orbital. The three sp 2 orbitals lie in a plane with ~120° angles. The p-orbital is perpendicular to this plane. When the carbon atoms approach each other, two of the sp 2 orbitals overlap to form a sigma bond.
Carbon is one of the few elements that can form long chains of its own atoms, a property called catenation.This coupled with the strength of the carbon–carbon bond gives rise to an enormous number of molecular forms, many of which are important structural elements of life, so carbon compounds have their own field of study: organic chemistry.