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The most common chloralkali process involves the electrolysis of aqueous sodium chloride (a brine) in a membrane cell. A membrane, such as Nafion, Flemion or Aciplex, is used to prevent the reaction between the chlorine and hydroxide ions. Basic membrane cell used in the electrolysis of brine.
Chlorine can also be produced by the electrolysis of a solution of potassium chloride, in which case the co-products are hydrogen and caustic potash (potassium hydroxide). There are three industrial methods for the extraction of chlorine by electrolysis of chloride solutions, all proceeding according to the following equations:
The first type, shown on the right and left of the diagram, uses an electrolyte of sodium chloride solution, a graphite anode (A), and a mercury cathode (M). The other type of cell, shown in the center of the diagram, uses an electrolyte of sodium hydroxide solution, a mercury anode (M), and an iron cathode (D). The mercury electrode is common ...
Electrolysis of iron can eliminate direct emissions and further reduce emissions if the electricity is created from green energy. The small-scale electrolysis of iron has been successfully reported by dissolving it in molten oxide salts and using a platinum anode. [52] Oxygen anions form oxygen gas and electrons at the anode.
In the chloralkali process (electrolysis of brine) a water/sodium chloride mixture is only half the electrolysis of water since the chloride ions are oxidized to chlorine rather than water being oxidized to oxygen. Thermodynamically, this would not be expected since the oxidation potential of the chloride ion is less than that of water, but the ...
The water used is usually brackish water or brine (i.e. a solution with >0.5% salinity). In these cases, additional contaminant chemicals may be present in the water feed. The low voltage DC current still performs electrochlorination. The excess chemicals are left untouched and can be easily discarded. [2]
Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water.In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for brining foods) up to about 26% (a typical saturated solution, depending on temperature).
Salt water chlorination is a process that uses dissolved salt (1000–4000 ppm or 1–4 g/L) for the chlorination of swimming pools and hot tubs.The chlorine generator (also known as salt cell, salt generator, salt chlorinator, or SWG) uses electrolysis in the presence of dissolved salt to produce chlorine gas or its dissolved forms, hypochlorous acid and sodium hypochlorite, which are already ...