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In organic chemistry, a ketone / ˈ k iː t oʊ n / is an organic compound with the structure R−C(=O)−R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group −C(=O)− (a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' are methyl), with the formula (CH 3) 2 CO ...
The Luche reduction can be conducted chemoselectively toward ketone in the presence of aldehydes or towards α,β-unsaturated ketones in the presence of a non-conjugated ketone. [5] An enone forms an allylic alcohol in a 1,2-addition, and the competing conjugate 1,4-addition is suppressed.
Other carbonyl (C=O) containing classes that are not ketones: Aldehydes ('R'C(=O)H; Esters (R 1-C(=O)O-R 2) Amides (R 1-C(=O)N-R 2 R 3) Subcategories.
The CBS reduction has proven to be an effective and powerful method to reduce a wide range of different types of ketones in both a stereoselective and chemoselective manner. Substrates include a large variety of aryl-aliphatic, di-aliphatic, di-aryl, α,β unsaturated enone and ynone systems, as well as ketones containing heteroatoms.
For organic compounds containing heteroatoms (other than C and H), the list of unsaturated groups is long but some common types are: carbonyl, e.g. ketones, aldehydes, esters, carboxylic acids (unsaturated) vs alcohol or ether (saturated) nitrile (unsaturated) vs amine (saturated) nitro (unsaturated) vs amine (saturated)
Here's what you'll need to toss in the trash to avoid temptation: all grains, legumes, dairy (unless it's all-natural butter), refined and processed foods, vegetable oils and trans fats, and, of ...
As you may know, the keto diet is essentially a high-fat, low-carb diet that puts your body into a metabolic state called ketosis. Basically, your body already burns carbohydrates for energy.
K — ketoacidosis, ketones generated from starvation, alcohol, and diabetic ketoacidosis; The mnemonic MUDPILES is commonly used to remember the causes of increased anion gap metabolic acidosis. [5] [6] M — Methanol; U — Uremia (chronic kidney failure) D — Diabetic ketoacidosis
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