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The K ATRP value depends on the homo-cleavage energy of the alkyl halide and the redox potential of the Cu catalyst with different ligands. Given two alkyl halides (R 1-X and R 2-X) and two ligands (L 1 and L 2), there will be four combinations between different alkyl halides and ligands. Let K ij ATRP refer to the K ATRP value for R i-X and L ...
Download as PDF; Printable version; In other projects Wikidata item; Appearance. move to sidebar hide. ATRP may refer to: GTRI Agricultural Technology Research ...
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In the case of RDRP reactions in the presence of Cu(0), one of the mechanistic models proposed in the literature is called the supplemental activator and reducing agent atom-transfer radical polymerization (SARA ATRP). [10] [13] [14] The SARA ATRP is characterized by the traditional ATRP reactions of activation by Cu(I) and deactivation by Cu ...
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The steady-state concentration of the growing polymer chains is 10 −7 M by order of magnitude, and the average life time of an individual polymer radical before termination is about 5–10 s. A drawback of the conventional radical polymerization is the limited control of chain architecture, molecular weight distribution, and composition.