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The T-V diagram of the rubber band experiment. The decrease in the temperature of the rubber band in a spontaneous process at ambient temperature can be explained using the Helmholtz free energy = where dF is the change in free energy, dL is the change in length, τ is the tension, dT is the change in temperature and S is the entropy.
Charles Haldat made some penetrating criticisms of the reproducibility of Rumford's results [15] and it is possible to see the whole experiment as somewhat tendentious. [16] However, the experiment inspired the work of James Prescott Joule in the 1840s. Joule's more exact measurements were pivotal in establishing the kinetic theory at the ...
The Rüchardt experiment, [1] [2] [3] invented by Eduard Rüchardt, is a famous experiment in thermodynamics, which determines the ratio of the molar heat capacities of a gas, i.e. the ratio of (heat capacity at constant pressure) and (heat capacity at constant volume) and is denoted by (gamma, for ideal gas) or (kappa, isentropic exponent, for real gas).
Schematic figure of Maxwell's demon thought experiment. Maxwell's demon is a thought experiment that appears to disprove the second law of thermodynamics. It was proposed by the physicist James Clerk Maxwell in 1867. [1] In his first letter, Maxwell referred to the entity as a "finite being" or a "being who can play a game of skill with the ...
In controlled experiments, the effect can entirely be explained by undercooling and the time of freezing was determined by what container was used. [12] Experimental results confirming the Mpemba effect have been criticized for being flawed, not accounting for dissolved solids and gasses, and other confounding factors.
Thermodynamics is a branch of physics ... influence on the modern versions of thermodynamics are the Berlin school, ... performed experiments ...
The Joule expansion, treated as a thought experiment involving ideal gases, is a useful exercise in classical thermodynamics. It provides a convenient example for calculating changes in thermodynamic quantities, including the resulting increase in entropy of the universe ( entropy production ) that results from this inherently irreversible process.
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.