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Electrolysis refers to the breakdown of substances using an electric current. This removes impurities in a substance that an electric current is run through; Sublimation is the process of changing of any substance (usually on heating) from a solid to a gas (or from gas to a solid) without passing through liquid phase. In terms of purification ...
[8] [9] Mixtures differ from chemical compounds in the following ways: The substances in a mixture can be separated using physical methods such as filtration, freezing, and distillation. There is little or no energy change when a mixture forms (see Enthalpy of mixing). The substances in a mixture keep their separate properties.
The figure shows the schematic P-T diagram of a pure substance (as opposed to mixtures, which have additional state variables and richer phase diagrams, discussed below). The commonly known phases solid , liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist.
While the term chemical substance is a precise technical term that is synonymous with chemical for chemists, the word chemical is used in general usage to refer to both (pure) chemical substances and mixtures (often called compounds), [14] and especially when produced or purified in a laboratory or an industrial process.
An ideal mixture is any in which the arithmetic mean (with respect to mole fraction) of the two pure substances is the same as that of the final mixture. Among other important thermodynamic simplifications, this means that enthalpy of mixing is zero: Δ H m i x , i d e a l = 0 {\displaystyle \Delta H_{mix,ideal}=0} .
For pure elements or compounds, e.g. pure copper, pure water, etc. the liquidus and solidus are at the same temperature, and the term melting point may be used. There are also some mixtures which melt at a particular temperature, known as congruent melting. One example is eutectic mixture. In a eutectic system, there is particular mixing ratio ...
Some mixtures will readily form solid solutions over a range of concentrations, while other mixtures will not form solid solutions at all. The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in
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