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The inelastic mean free path of electrons can roughly be described by a universal curve that is the same for all materials. [1] [3] The knowledge of the IMFP is indispensable for several electron spectroscopy and microscopy measurements. [4]
An electron transport chain (ETC [1]) is a series of protein complexes and other molecules which transfer electrons from electron donors to electron acceptors via redox reactions (both reduction and oxidation occurring simultaneously) and couples this electron transfer with the transfer of protons (H + ions) across a membrane.
In physics, mean free path is the average distance over which a moving particle (such as an atom, a molecule, or a photon) travels before substantially changing its direction or energy (or, in a specific context, other properties), typically as a result of one or more successive collisions with other particles.
Especially in proteins, electron transfer often involves hopping of an electron from one redox-active center to another one. The hopping pathway, which can be viewed as a vector, guides and facilitates ET within an insulating matrix. Typical redox centers are iron-sulfur clusters, e.g. the 4Fe-4S ferredoxins. These sites are often separated by ...
Electrons are removed from excited chlorophyll molecules and transferred through a series of intermediate carriers to ferredoxin, a water-soluble electron carrier. As in PSII, this is a solid-state process that operates with 100% efficiency. There are two different pathways of electron transport in PSI.
In mammals, this metabolic pathway is important in beta oxidation of fatty acids and catabolism of amino acids and choline, as it accepts electrons from multiple acetyl-CoA dehydrogenases. [ 32 ] [ 33 ] In plants, ETF-Q oxidoreductase is also important in the metabolic responses that allow survival in extended periods of darkness.
The two charge carriers, electrons and holes, will typically have different drift velocities for the same electric field. Quasi-ballistic transport is possible in solids if the electrons are accelerated across a very small distance (as small as the mean free path), or for a very short time (as short as the mean free time). In these cases, drift ...
Illustration of the malate–aspartate shuttle pathway. The malate–aspartate shuttle (sometimes simply the malate shuttle) is a biochemical system for translocating electrons produced during glycolysis across the semipermeable inner membrane of the mitochondrion for oxidative phosphorylation in eukaryotes.