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Sulfites used in food processing (but not as a preservative) are required to be listed if they are not incidental additives (21 CFR 101.100(a)(3)), and if there are more than 10 ppm in the finished product (21 CFR 101.100(a)(4)) On July 8, 1986, sodium bisulfite (and other sulfites : "The chemicals affected by the order are sulfur dioxide ...
The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, [1] its salts are widely used. Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives. [2] When in food or drink, sulfites are often lumped together with sulfur dioxide. [3]
Ultrafiltration can also be used to separate lignosulfonates from the spent pulping liquid. [1] A list of CAS numbers for the various metal salts of lignosulfonate is available. [4] The electrophilic carbocations produced during ether cleavage react with bisulfite ions (HSO 3 −) to give sulfonates. R-O-R' + H + → R + + R'OH R + + HSO 3 − ...
Chemical processes quickly followed, first with Julius Roth's use of sulfurous acid to treat wood in 1857, followed by Benjamin Chew Tilghman's US patent on the use of calcium bisulfite, Ca(HSO 3) 2, to pulp wood in 1867. [3] Almost a decade later in 1874 the first commercial sulfite pulp mill was built in Sweden.
The 4S pathway is a sulfur-specific metabolic pathway of oxidative desulfurization that converts dibenzothiophene (DBT) into 2-hydroxybiphenyl and sulfite.It uses a total of four NADH molecules (three required by DszD to generate FMNH 2 and a fourth to regenerate the FMN-oxide byproduct of DszA) and three molecules of oxygen, thus producing NAD + and water as byproducts.
Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3.Sodium bisulfite is not a real compound, [2] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
Another use of bisulfite in organic chemistry is as a mild reducing agent, for example to remove traces or excess amounts of chlorine, bromine, iodine, hypochlorite salts, osmate esters, chromium trioxide and potassium permanganate. Sodium bisulfite is a decoloration agent in purification procedures because it reduces strongly coloured ...
Although the equilibrium lies far to the left, evaporation of a bisulfite salt will produce a substantial amount of disulfite. [6] Disulfite is the conjugate base of disulfurous acid (pyrosulfurous acid), which originates from sulfurous acid in accordance with the dehydration reaction above: 2 H 2 SO 3 → 2 HSO − 3 + 2 H + → H 2 S 2 O 5 ...